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Beilstein J. Org. Chem. 2012, 8, 683–692, doi:10.3762/bjoc.8.76
Graphical Abstract
Scheme 1: Synthesis of 3-azidothiophene 2.
Scheme 2: One-pot, two-step procedure to give a dithienyl-1,2,3-triazole co-oligomer 5. See Table 1 for detailed con...
Scheme 3: Synthesis of 1,4-bis[4-(thiophen-2-yl)-1H-1,2,3-triazol-1-yl]-benzene 21.
Figure 1: UV–vis spectra of 5, 10 and 11 (a) and 12–14 (b) in dichloromethane ([c] = 5 × 10−5 M) at room temp...
Figure 2: HOMO–LUMO energy level diagram for thiophene–triazole co-oligomers 5, 6, 10–14.
Figure 3: Cyclic voltammogram of bithienyl-triazole 14 in dichloromethane/TBAPF6 (0.1 M) versus Fc/Fc+ at 100...